Themed collection Chemical Communications HOT Articles 2024
Carbon–carbon bond formation using aromatics from biomass
This highlight provides an overview of methods for carbon–carbon bond formation using sustainable aromatics derived from biomass.
Chem. Commun., 2024, Advance Article
https://doi.org/10.1039/D4CC05664G
New Frontiers in phosphorothioate formation: harnessing inorganic phosphorus sources
This review highlights the latest advancements in the synthesis of phosphorothioates and their derivatives from inorganic phosphorus sources, focusing on their applicability, mechanisms, current limitations, and potential future directions.
Chem. Commun., 2024, Advance Article
https://doi.org/10.1039/D4CC05854B
Unveiling the potential of MOF-based single-atom photocatalysts for the production of clean fuel and valuable chemical
Our highlight provides a comprehensive/insightful review on the achievement of combining a MOF and single atoms to generate high-performance photocatalysts for energy-related reactions.
Chem. Commun., 2024,60, 10989-10999
https://doi.org/10.1039/D4CC03479A
Dual-stimuli responsive theranostic agents based on small molecules
This Highlight summarizes the recent progress of dual-stimuli responsive theranostic agents based on small molecules.
Chem. Commun., 2024,60, 9860-9870
https://doi.org/10.1039/D4CC02565B
Functional implications of unusual NOS and SONOS covalent linkages found in proteins
Novel NOS linkages stabilize protein tertiary and quaternary structures and may be as prevalent as disulfide bonds. They regulate enzyme activity and have other important roles.
Chem. Commun., 2024,60, 9463-9471
https://doi.org/10.1039/D4CC03191A
Value addition of MXenes as photo-/electrocatalysts in water splitting for sustainable hydrogen production
Recent advances in the use of MXenes for (photo)electrocatalytic water splitting applications are reviewed.
Chem. Commun., 2024,60, 8789-8805
https://doi.org/10.1039/D4CC01811G
Electrocatalytic water-to-oxygenates conversion: redox-mediated versus direct oxygen transfer
Elucidating the oxygen transfer route can facilitate the development of electro-catalytic oxygenation reactions. Herein, we introduce oxygen transfer routes including the redox-mediated pathway and the direct oxygen transfer (DOT) method.
Chem. Commun., 2024,60, 7523-7534
https://doi.org/10.1039/D4CC01960A
Electrifying oxidation of ethylene and propylene
This highlight discusses the advantages of various oxidation methods for improved performance of the electrochemical oxidation of ethylene and propylene, and provides an overview of current challenges and problems requiring further efforts.
Chem. Commun., 2024,60, 6703-6716
https://doi.org/10.1039/D4CC02025A
Mechanism-based and data-driven modeling in cell-free synthetic biology
This highlight discusses state-of-the-art mechanism-based modeling and machine-learning approaches in cell-free synthetic biology and their potential for designing and optimizing novel genetic circuits.
Chem. Commun., 2024,60, 6466-6475
https://doi.org/10.1039/D4CC01289E
Recent advances in C(sp3)–N bond formation via metallaphoto-redox catalysis
In this review, the state-of-the-art advances in radical-involved C(sp3)–N bond formation via metallaphotoredox catalysis have been highlighted, which are organized according to different catalytic modes, reaction types, and substrate classes.
Chem. Commun., 2024,60, 6340-6361
https://doi.org/10.1039/D4CC01969E
Recent developments in photocatalytic production of hydrogen peroxide
This highlight article summarizes the recent developments and challenges in photocatalytic production of hydrogen peroxide and looks forward to the development direction of this field.
Chem. Commun., 2024,60, 5354-5368
https://doi.org/10.1039/D4CC01577K
Recent advances in electrosynthesis of H2O2via two-electron oxygen reduction reaction
This review provides an electrosynthesis strategy of H2O2via the 2e− ORR, covering aspects of reaction mechanisms, performance assessment, catalyst engineering, and setups for scaling up H2O2 production.
Chem. Commun., 2024,60, 5232-5244
https://doi.org/10.1039/D4CC01476F
Enantioselective merged gold/organocatalysis
This highlight demonstrates the state of the art in the field of the enantioselective merged gold/organocatalysis by leveraging the unique reactivity of each catalyst.
Chem. Commun., 2024,60, 3607-3623
https://doi.org/10.1039/D4CC00114A
Visual monitoring of biocatalytic processes using small molecular fluorescent probes: strategies-mechanisms-applications
Real-time monitoring of biocatalytic-based processes is significantly improved and simplified when they can be visualized.
Chem. Commun., 2024,60, 2716-2731
https://doi.org/10.1039/D3CC05626K
Catalysts and electrolyzers for the electrochemical CO2 reduction reaction: from laboratory to industrial applications
To cope with the environmental pollution and energy shortage, reducing carbon dioxide molecules and producing fuels and chemicals via electrocatalytic methods, is one of the effective pathways to achieve carbon neutrality.
Chem. Commun., 2024,60, 1207-1221
https://doi.org/10.1039/D3CC05453E
Compartmentalised single-chain nanoparticles and their function
This review focuses on the latest developments of single-chain nanoparticles bearing internal compartments (sized ∼1 nm), comparable to proteins and enzymes. We focus on the synthesis, detailed analyses and applications of such compartments.
Chem. Commun., 2024,60, 14332-14345
https://doi.org/10.1039/D4CC04387A
1,3-Bishomocubane: a kinetic rock, a thermodynamic powerhouse and a compelling chiral synthetic scaffold
Over the last several decades, saturated polycyclic cage compounds have remained a point of interest for organic chemists because of their unique characteristics and reactivity.
Chem. Commun., 2024,60, 14142-14154
https://doi.org/10.1039/D4CC04290E
Intramolecularly remote functional group migration reactions involving free radicals
This feature article summarizes our achievements in radical-mediated intramolecular functional group migration reactions, aiming to provide a comprehensive understanding of the progress in this emerging area.
Chem. Commun., 2024, Advance Article
https://doi.org/10.1039/D4CC05739B
Iron-catalysed intramolecular C(sp3)–H amination of alkyl azides
This review summarizes recent major advances in iron-catalysed C–H aminations of alkyl azides through iron–alkylnitrene/alkylimido intermediates to access various N-heterocycles.
Chem. Commun., 2024,60, 13998-14011
https://doi.org/10.1039/D4CC04169K
Rational design of water splitting electrocatalysts through computational insights
This article highlights recent advances in computational design of water splitting electrocatalysts, and emphasizes the unique insights and predictive power of computational design for improving catalyst performance.
Chem. Commun., 2024, Advance Article
https://doi.org/10.1039/D4CC05117C
Copper nanoclusters: emerging photoredox catalysts for organic bond formations
In this feature article, we provide an overview of the photocatalytic capabilities of copper-based nanoclusters for organic bond-forming reactions.
Chem. Commun., 2024,60, 13858-13866
https://doi.org/10.1039/D4CC04774E
Upcycling of waste polyesters for the development of a circular economy
Progress in chemical recycling of waste polyesters (waste plastic refinery) was reviewed and prospected, newly reported thermal catalysis, photocatalysis, electrocatalysis, and biocatalysis in the recycle of waste PET-based product were introduced.
Chem. Commun., 2024,60, 13832-13857
https://doi.org/10.1039/D4CC04780J
Exploiting hydrogenases for biocatalytic hydrogenations
The ability of hydrogenase enzymes to activate H2 with excellent selectivity leads to many interesting possibilities for biotechnology driven by H2 as a clean reductant.
Chem. Commun., 2024,60, 13667-13677
https://doi.org/10.1039/D4CC04525D
Multiphase coacervates: mimicking complex cellular structures through liquid–liquid phase separation
This review summarizes recent advancements in the study of multiphase coacervates, focusing on design strategies, underlying mechanisms, structural control, and their applications in biomimetics.
Chem. Commun., 2024,60, 13169-13178
https://doi.org/10.1039/D4CC04533E
Common ground and divergence: OLED emitters as photocatalysts
Many photocatalysts were initially developed or used as emitters for organic light emitting diodes (OLEDs). Requirements for photocatalysts and OLED emitters overlap in many aspects but diverge in some.
Chem. Commun., 2024,60, 12951-12963
https://doi.org/10.1039/D4CC04409F
Advances in the self-organized total synthesis of natural products
In this review, we account for the definition, delimitation, and categorization of self-organized total synthesis and then elucidate a comprehensive understanding of this synthetic strategy based on our intensive explorations.
Chem. Commun., 2024,60, 12803-12815
https://doi.org/10.1039/D4CC04288C
Biomimetic light-harvesting antennas via the self-assembly of chemically programmed chlorophylls
This feature article describes strategies for constructing supramolecular aggregates of (semi)synthetic dyes, particularly chlorophyll derivatives to mimic the photosynthetic light-harvesting antennas.
Chem. Commun., 2024,60, 12513-12524
https://doi.org/10.1039/D4CC04363D
Recent advances in catalytic enantioselective construction of monofluoromethyl-substituted stereocenters
This feature article comprehensively summarizes the recent advances in catalytic enantioselective construction of monofluoromethyl-substituted stereocenters.
Chem. Commun., 2024,60, 12302-12314
https://doi.org/10.1039/D4CC03788J
Spot the difference in reactivity: a comprehensive review of site-selective multicomponent conjugation exploiting multi-azide compounds
This review outlines methods and strategies to exploit specific azide positions for molecular conjugation in the presence of multiple azido groups. Illustrative examples spanning di-, tri- and tetraazide click scaffolds are included.
Chem. Commun., 2024,60, 12062-12100
https://doi.org/10.1039/D4CC03359K
Development of chemiluminescent systems and devices for analytical applications
Chemiluminescent luminophores, coreactants, catalysts and sonochemiluminescence devices are highlighted.
Chem. Commun., 2024,60, 11837-11848
https://doi.org/10.1039/D4CC04414B
Metal-free small molecule-based piezoelectric energy harvesters
The recent progress in the design of metal-free small-molecule derived piezoelectric materials and their utilization as all-organic piezoelectric energy harvesters has been discussed in this feature article.
Chem. Commun., 2024,60, 11655-11672
https://doi.org/10.1039/D4CC03939D
Advances in designing efficient electrocatalysts for nitrate reduction from a theoretical perspective
The electrochemical nitrate reduction reaction to ammonia (eNO3−RR) is a potential way for harmonizing the nitrogen cycle. This feature article summarizes the recent advances in electrocatalyst design for the eNO3−RR from a theoretical perspective.
Chem. Commun., 2024,60, 11642-11654
https://doi.org/10.1039/D4CC04046E
Heterogeneous catalysis of methane hydroxylation with nearly total selectivity under mild conditions
Recent advancements in methane hydroxylation catalysis have achieved nearly total selectivity. A deeper understanding of catalyst design, reaction mechanism, and parameter optimization is crucial for minimizing CO2 and boosting oxygenate yield.
Chem. Commun., 2024,60, 11034-11051
https://doi.org/10.1039/D4CC02802C
Supramolecular light-harvesting systems utilizing tetraphenylethylene chromophores as antennas
This comprehensive Feature Article summarizes the recent progress of supramolecular light-harvesting systems utilizing tetraphenylethylene (TPE) chromophores as antennas.
Chem. Commun., 2024,60, 10064-10079
https://doi.org/10.1039/D4CC03693J
Cationic ligands – from monodentate to pincer systems
Incorporation of cationic ligands within pincer frameworks allowed to develop them from obscure peculiarities into a diverse class of ancillary ligands.
Chem. Commun., 2024,60, 9871-9906
https://doi.org/10.1039/D4CC01489H
Glycosylation with sulfoxide-based glycosyl donors
This feature article elucidates the development and notable progress of glycosyl sulfoxide-based glycosylation reactions, with a specific emphasis on cases where sulfinyl groups are situated either directly at the anomeric position or more distally.
Chem. Commun., 2024,60, 8670-8683
https://doi.org/10.1039/D4CC02838D
Mechanistic insights into facilitating reductive elimination from Ni(II) species
The possible modes have been summarized to disclose the reductive elimination from Ni(II) species.
Chem. Commun., 2024,60, 8008-8019
https://doi.org/10.1039/D4CC02667E
Ru(0)-catalysed synthesis of borylated polyene building blocks by cross-dimerisation toward cross-coupling
A series of borylated polyenes is synthesised by cross-dimerisation as a synthetic building block for cross-coupling reactions.
Chem. Commun., 2024,60, 7672-7686
https://doi.org/10.1039/D4CC02566K
Recent advances in circularly polarized luminescence of planar chiral organic compounds
This review overviews recent research on circularly polarized luminescence from planar chiral organic compounds, focusing on their synthetic strategies, properties and applications.
Chem. Commun., 2024,60, 6728-6740
https://doi.org/10.1039/D4CC01698J
Metal–organic framework (MOF)-based materials for pyroptosis-mediated cancer therapy
This manuscript summarized the recent progress of MOF-based pyroptosis inducers in immunotherapy.
Chem. Commun., 2024,60, 6476-6487
https://doi.org/10.1039/D4CC02084G
Hydrogen bond types which do not fit accepted definitions
There are various interactions that either partially fit or do not fit the currently accepted definitions of the hydrogen bond.
Chem. Commun., 2024,60, 6239-6255
https://doi.org/10.1039/D4CC01769B
All-atom molecular dynamics simulations of polymer and polyelectrolyte brushes
New discoveries on polymer and polyelectrolyte brush systems and the corresponding brush-supported ions and water, arising from employing all-atom molecular dynamics simulations, have been thoroughly reviewed.
Chem. Commun., 2024,60, 6093-6129
https://doi.org/10.1039/D4CC01557F
Molecule engineering strategy of toll-like receptor 7/8 agonists designed for potentiating immune stimuli activation
We highlighted the recent research progress concerning the molecule engineering strategy of toll-like receptor 7/8 agonists for enhancing immunotherapy, including our research work and some related emerging works.
Chem. Commun., 2024,60, 5474-5485
https://doi.org/10.1039/D4CC00792A
Cascade ring expansion reactions for the synthesis of medium-sized rings and macrocycles
Recent advances in the development of cascade ring expansion reactions for the synthesis of medium-sized rings and macrocycles are described.
Chem. Commun., 2024,60, 4999-5009
https://doi.org/10.1039/D4CC01303D
Cooperative small molecule activation by apolar and weakly polar bonds through the lens of a suitable computational protocol
Through the magnifying glass of a suitable computational protocol, both support and guidance of experimental advances in small molecules activation mediated by apolar and weakly polar bonds are made possible.
Chem. Commun., 2024,60, 1222-1238
https://doi.org/10.1039/D3CC05614G
Artificial transmembrane potassium transporters: designs, functions, mechanisms and applications
In this review, we provide the very first comprehensive exposition of artificial potassium transporters developed mostly over the past ten years.
Chem. Commun., 2024,60, 482-500
https://doi.org/10.1039/D3CC04488B
Emerging sensing platforms based on Cucurbit[n]uril functionalized gold nanoparticles and electrodes
Cucurbit[n]uril functionalized gold nanoparticles and electrodes facilitate the development of sensing platforms based on recognition tunneling, surface-enhanced Raman spectroscopy, single molecule force spectroscopy, and electrochemical methods.
Chem. Commun., 2024,60, 150-167
https://doi.org/10.1039/D3CC04851A
Sample transformation in online separations: how chemical conversion advances analytical technology
Sample transformation can be used to provide insights into the properties of complex samples.
Chem. Commun., 2024,60, 36-50
https://doi.org/10.1039/D3CC03599A
Nanosensor quantitative monitoring of ROS/RNS homeostasis in single phagolysosomes of macrophages during bactericidal processes
In situ, quantitative, selective, and sub-millisecond dynamic detection of the four primary ROS/RNS (ONOO−, H2O2, NO, and NO2−) in individual phagolysosomes during sterilization of RAW 264.7 macrophages was achieved by SiC@Pt nanowire electrodes.
Chem. Commun., 2024, Advance Article
https://doi.org/10.1039/D4CC05423G
Li2NbHO2: a new transition-metal oxyhydride with rock-salt-type structure
We successfully synthesized Li2NbHO2, the first example of a rock-salt-type transition-metal oxyhydride. Galvanostatic charge/discharge tests revealed that Li2NbHO2 functions as an electrode for lithium secondary batteries.
Chem. Commun., 2024,60, 14388-14390
https://doi.org/10.1039/D4CC05503A
Hydrazone-linked covalent organic frameworks for fluorescence detection of Hg2+
A hydrazone-linked COF (DvDf-C3XJ-COF) with hydrogen-bond reinforcement and abundant coordination sites was synthesized, exhibiting strong fluorescence and high sensitivity/selectivity for Hg2+ detection, with a detection limit of 1.65 × 10−6 M.
Chem. Commun., 2024,60, 14391-14394
https://doi.org/10.1039/D4CC05468G
Molecular acceptor engineering to design precisely NIR type I photosensitizer for efficient PDT-based synergistic therapy
Chem. Commun., 2024, Accepted Manuscript
https://doi.org/10.1039/D4CC06079B
Surface-mounted carbon quantum dots onto photonic crystals generating dual structural-fluorescent color rendering
Dual structural-fluorescent color rendering photonic crystals (PCs) based on ZIF-8/TiO2 1D PCs and PEI-capped CQDs.
Chem. Commun., 2024, Advance Article
https://doi.org/10.1039/D4CC05618C
Pd(II)-catalyzed regioselective ring opening/[3+2] annulation reaction of enaminones with cyclopropenones: divergent synthesis of γ-butenolides and γ-lactams
Highly functionalized γ-butenolides and γ-lactams were efficiently synthesized via a Pd(II)-catalyzed, regioselective and skeleton-controllable ring opening/[3+2] annulation reaction between readily available enaminones and cyclopropenones.
Chem. Commun., 2024, Advance Article
https://doi.org/10.1039/D4CC05895J
A cobalt-tetraphenylporphyrin-based hypercrosslinked polymer for efficient CO2 photoreduction to CO
One of the main impediments during the CO2 photocatalytic reduction process is controlling a particular product's selectivity while keeping a high conversion rate.
Chem. Commun., 2024, Advance Article
https://doi.org/10.1039/D4CC05331A
Synthesis of heteroleptic bis-phosphine bis-NHC iron (0) complexes: a strategy to enhance small molecule activation
We report low-valent iron complexes containing bis-NHC and bis-phosphine donor ligands that coordinate and strongly activate N2 and CO.
Chem. Commun., 2024,60, 14037-14040
https://doi.org/10.1039/D4CC05463F
CO insertion enabled γ-C(sp3)–H heteroarylative carbonylation of tertiary alcohols via heteroaryl migration
A carbonylative γ-C(sp3)–H functionalization of alcohols via migration of heteroaryl groups to produce 1,4-diketones has been developed.
Chem. Commun., 2024,60, 14034-14036
https://doi.org/10.1039/D4CC05361C
What could be the low-temperature limit of atomic layer deposition of platinum using MeCpPtMe3 and oxygen?
Room-temperature atmospheric-pressure ALD enables the deposition of highly dispersed Pt sub-nanometer clusters on a gram-scale quantity of TiO2 nanopowder.
Chem. Commun., 2024,60, 14045-14048
https://doi.org/10.1039/D4CC04679J
On site portable detection of gaseous I2 using green and pollution-free electrochemical methods
A poly(ionic liquid) (PIL) probe material that is rich in I2 interaction sites was developed, and a green and pollution-free electrochemical method was used to detect gaseous I2 using PIL-based film sensors.
Chem. Commun., 2024,60, 14041-14044
https://doi.org/10.1039/D4CC05418K
Asymmetric cyclopropanation via an electro-organocatalytic cascade
The work demonstrates the successful merger of electrochemistry with asymmetric iminium ion organocatalysis.
Chem. Commun., 2024,60, 14026-14029
https://doi.org/10.1039/D4CC05092D
Nickel-catalyzed silylation of aryl thianthrenium salts with silylzinc pivalates
A modular nickel-catalyzed silylation of aryl thianthrenium salts with salt-stabilized silylzinc pivalates is disclosed, thus providing an expedient route to rapidly incorporate silyl motifs into aromatics.
Chem. Commun., 2024, Advance Article
https://doi.org/10.1039/D4CC05395H
Interphase formation versus fluoride-ion insertion in tunnel-structured transition metal antimonites
Understanding the competitive nature of insertion versus interphase formation is key to the design of insertion electrodes of fluoride-ion batteries.
Chem. Commun., 2024, Advance Article
https://doi.org/10.1039/D4CC04331F
Cereblon-recruiting proteolysis targeting chimeras (PROTACs) can determine the selective degradation of HDAC1 over HDAC3
Cereblon-recruiting PROTACs can degrade HDAC1 with selectivity over HDAC3.
Chem. Commun., 2024,60, 13879-13882
https://doi.org/10.1039/D4CC05138F
Chemical oxidation of a double-twisted nanographene
A dicationic double-twisted nanographene exhibited an intense NIR-II absorption band tailing to 1500 nm as well as a high dissymmetry factor of −2.09% at 1443 nm.
Chem. Commun., 2024,60, 13875-13878
https://doi.org/10.1039/D4CC05264A
Diamidocarbene-derived palladium and nickel–sulfur clusters
Tetranuclear palladium and nickel–sulfur clusters were synthesized using a diamidocarbene-derived, redox-active carbon disulfide ligand.
Chem. Commun., 2024,60, 13867-13870
https://doi.org/10.1039/D4CC04582C
Detecting single-point isomeric differences in polymer chains by MOF column chromatography
A MOF-packed column can detect a pinpoint difference in a polymer chain through a nanopore-threading recognition mechanism.
Chem. Commun., 2024,60, 13690-13693
https://doi.org/10.1039/D4CC04902K
A giant macrocycle overcomes the post-treatment phototoxicity of photofrin through host–guest complexation
Here we reported a supramolecular sequestration strategy to overcome the post-treatment phototoxicity of photofrin via direct host–guest complexation.
Chem. Commun., 2024,60, 13686-13689
https://doi.org/10.1039/D4CC04777J
A ternary composite nanofiber-derived thin membrane electrolyte for solid-state Li metal batteries
We develop a novel membrane electrolyte comprising h-BN-doped PEO modified PVDF-HFP-nanofibers with high ionic conductivity (3.3 × 10−4 S cm−1) and Li+ transference number (0.74), endowing solid LiFePO4//Li batteries with excellent cyclability.
Chem. Commun., 2024,60, 13530-13533
https://doi.org/10.1039/D4CC04550E
Blue photoluminescence of wide-bandgap polystyrenesulfonate materials
Blue photoluminescence (PL) was observed in polystyrene sulfonic acid solution (PSS) for the first time. And the diversity and tunability of its PL properties were revealed.
Chem. Commun., 2024,60, 13187-13190
https://doi.org/10.1039/D4CC04751F
Cobalt-catalyzed dithiolation of unactivated alkenes with thiols: facile access to diverse vicinal dithioethers
A simple cobalt-catalytic aerobic approach for the direct dithiolation of unactivated alkenes with thiols has been established, enabling efficient access to symmetric and unsymmetric vicinal dithioethers under mild reaction conditions.
Chem. Commun., 2024,60, 13191-13194
https://doi.org/10.1039/D4CC04746J
About this collection
This ongoing web-collection features the articles published in ChemComm in 2024 that have been marked as HOT by our Editors and trusted Reviewers. Many Congratulations to all those featured!