Issue 92, 2022
From the journal:

Chemical Communications

Hydrophobicity and dielectric properties across an isostructural family of MOFs: a duet or a duel?†

Simona Sorbara,‡a   Soumya Mukherjee, ORCID logo ‡*b   Andreas Schneemann, ORCID logo c   Roland A. Fischer ORCID logo *b  and  Piero Macchi ORCID logo *a  

* Corresponding authors

a Department of Chemistry, Materials and Chemical Engineering, Polytechnics of Milan, Via Mancinelli 7, 20131 Milan, Italy
E-mail: piero.macchi@polimi.it

b Technical University of Munich (TUM), TUM School of Natural Sciences, Department of Chemistry, Chair of Inorganic and Metal–Organic Chemistry, Catalysis Research Center (CRC), Munich, Germany
E-mail: soumya.mukherjee@tum.de, roland.fischer@tum.de

c Lehrstuhl für Anorganische Chemie I, Technische Universität Dresden, Bergstrasse 66, 01069 Dresden, Germany

Abstract

An isoreticular family of metal–organic frameworks is post-synthetically subjected to polymer grafting. Surface hydrophobicity analysis, adsorption experiments, and impedance spectroscopy characterise the water molecules adsorbed, both on the surface and in the pores, while resolving how molecular mobility is impacted.

Graphical abstract: Hydrophobicity and dielectric properties across an isostructural family of MOFs: a duet or a duel?

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Article information

DOI
https://doi.org/10.1039/D2CC04281A
Article type
Communication
Submitted
31 Jul 2022
Accepted
24 Oct 2022
First published
28 Oct 2022

Chem. Commun., 2022,58, 12823-12826

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Hydrophobicity and dielectric properties across an isostructural family of MOFs: a duet or a duel?

S. Sorbara, S. Mukherjee, A. Schneemann, R. A. Fischer and P. Macchi, Chem. Commun., 2022, 58, 12823 DOI: 10.1039/D2CC04281A

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