Issue 6, 2020

Alloy scattering of phonons

Abstract

Solid-solution alloy scattering of phonons is a demonstrated mechanism to reduce the lattice thermal conductivity. The analytical model of Klemens works well both as a predictive tool for engineering materials, particularly in the field of thermoelectrics, and as a benchmark for the rapidly advancing theory of thermal transport in complex and defective materials. This comment/review outlines the simple algorithm used to predict the thermal conductivity reduction due to alloy scattering, as to avoid common misinterpretations, which have led to a large overestimation of mass fluctuation scattering. The Klemens model for vacancy scattering predicts a nearly 10× larger scattering parameter than is typically assumed, yet this large effect has often gone undetected due to a cancellation of errors. The Klemens description is generalizable for use in ab initio calculations on complex materials with imperfections. The closeness of the analytic approximation to both experiment and theory reveals the simple phenomena that emerges from the complexity and unexplored opportunities to reduce thermal conductivity.

Graphical abstract: Alloy scattering of phonons

Article information

Article type
Focus
Submitted
10 Dec 2019
Accepted
22 Apr 2020
First published
22 Apr 2020

Mater. Horiz., 2020,7, 1452-1456

Author version available

Alloy scattering of phonons

R. Gurunathan, R. Hanus and G. J. Snyder, Mater. Horiz., 2020, 7, 1452 DOI: 10.1039/C9MH01990A

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