Issue 82, 2019

A Co8 metallacycle stabilized by double anion–π interactions

Abstract

Self-assembly reactions of CoII ions in the presence of the 2,2-bipyrimidine (bpym) ligand produced both a dinuclear and an octanuclear cation with the nuclearity being governed by hydrogen-bonding versus anion–π interactions between the anions and the ligands.

Graphical abstract: A Co8 metallacycle stabilized by double anion–π interactions

Supplementary files

Article information

Article type
Communication
Submitted
29 May 2019
Accepted
11 Jul 2019
First published
11 Jul 2019

Chem. Commun., 2019,55, 12356-12359

Author version available

A Co8 metallacycle stabilized by double anion–π interactions

D. I. Alexandropoulos, B. S. Dolinar, H. Xie, K. R. Vignesh and K. R. Dunbar, Chem. Commun., 2019, 55, 12356 DOI: 10.1039/C9CC04151F

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