Reactivity of the isolated catecholatoiron complex with O2 and the spectroscopic observation of the reversible catecholate ligand exchange reveal that a stable chelated catecholate species may be activated to be reactive with O2 in the catalytic system.
T. Funabiki, M. Ishikawa, Y. Nagai, J. Yorita and S. Yoshida, J. Chem. Soc., Chem. Commun., 1994, 1951 DOI: 10.1039/C39940001951
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