Trinuclear manganese or rhodium complexes of the trindenyl (Td) ligand undergo three separate 1 e–-oxidation reactions, with an abnormally large separation in potentials between the second and third oxidations of [Td{Rh3(cod)3}].
R. Winter, D. T. Pierce, W. E. Geiger and T. J. Lynch, J. Chem. Soc., Chem. Commun., 1994, 1949 DOI: 10.1039/C39940001949
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