The total synthesis of trioxilins 11,12-threo-TrXB3 has been extended to the corresponding trioxilins of the (8,11,12)-A3 type. The synthesis involves the allylic rearrangement of a protected TrXB3 derivative with a free 10-hydroxyl group under the Mitsunobu reaction conditions as the key step.
Total synthesis of trioxilins 11,12-threo-(8,11,12)-A3 through type B3 trioxilins
M. A. Lapitskaya, L. L. Vasiljeva, P. M. Demin and K. K. Pivnitsky, Mendeleev Commun., 2004, 14, 291 DOI: 10.1070/MC2004v014n06ABEH002004
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