Issue 11, 2000
From the journal:

Chemical Communications

The arched four-rung ladder structure of the unsolvated dilithium salt of N,N′-bis(trimethylsilyl)-2-aminobenzylamine, and its structural deformation on THF complexation

Régis M. Gauvin,a   Nathalie Kyritsakas,b   Jean Fischerb  and  Jacky Kress*a  

* Corresponding authors

a Laboratoire de Chimie des Métaux de Transition et de Catalyse, UMR 7513, Université Louis Pasteur, Institut Le Bel, 4 rue Blaise Pascal, Strasbourg Cedex, France.
E-mail: jkress@chimie.u-strasbg.fr

b Laboratoire de Cristallochimie et de Chimie Structurale, UMR 7513, Université Louis Pasteur, Institut Le Bel, 4 rue Blaise Pascal, Strasbourg Cedex, France

Abstract

The X-ray crystal structures of 2-Li(SiMe3)NC6H4CH2N(SiMe 3)Li 1 and 2-Li(SiMe3)NC6H4CH2N(SiMe 3)Li·THF 2 show that both compounds exist in the solid state as discrete dimers that display an analogous four-rung ladder core, allowing us to analyse the effect of THF coordination.

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Article information

DOI
https://doi.org/10.1039/B002004O
Article type
Communication
Submitted
09 Mar 2000
Accepted
02 May 2000
First published
17 May 2000

Chem. Commun., 2000, 965-966

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The arched four-rung ladder structure of the unsolvated dilithium salt of N,N′-bis(trimethylsilyl)-2-aminobenzylamine, and its structural deformation on THF complexation

R. M. Gauvin, N. Kyritsakas, J. Fischer and J. Kress, Chem. Commun., 2000, 965 DOI: 10.1039/B002004O

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