Neutral heterobinuclear triazenide-bridged complexes are oxidised to paramagnetic monocations; the electron distribution in the σ* metal–metal orbital of rhodium–iridium complexes may be controlled by the ancillary ligands at the two metals.
Redox-active heterobinuclear triazenide-bridged complexes; ancillary ligand control of electron distribution in a three-electron metal–metal bond
N. G. Connelly, O. D. Hayward, P. Klangsinsirikul, A. G. Orpen and P. H. Rieger, Chem. Commun., 2000, 963 DOI: 10.1039/B001764G
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