The conjugate addition reactions of lithiated N-p-tosyl S-phenyl-2-enyl sulfoximine 4 with cyclic and acyclic enones gives exclusively 1,4-α adducts, the reactions with acyclic enones are highly diastereoselective.
S. G. Pyne, Z. Dong, B. W. Skelton and A. H. White, J. Chem. Soc., Chem. Commun., 1994, 751 DOI: 10.1039/C39940000751
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