Charge reversal of electrophilic π-allylpalladium intermediates; carbonyl allylation by allylic acetates with PdCl2(PhCN)2–SnCl2
Abstract
Carbonyl allylation by stable allylic acetates with Pd0–SnCl2 occurred regio-, chemo-, and diastereoselectively to afford the corresponding homoallylic alcohols.
 
                



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