Issue 3, 1987

Iminium ions as initiators and allylsilanes as terminators in polyolefin cyclizations: total synthesis of (±)-yohimbone via a vinylogous aminomethano desilylation process

Abstract

A syntheses of (±)-yohimbone has been realized via a concerted iminium ion-induced polyolefin cyclization terminated by an allylsilane.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 185-186

Iminium ions as initiators and allylsilanes as terminators in polyolefin cyclizations: total synthesis of (±)-yohimbone via a vinylogous aminomethano desilylation process

P. A. Grieco and W. F. Fobare, J. Chem. Soc., Chem. Commun., 1987, 185 DOI: 10.1039/C39870000185

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