Sodium [N,N′-ethylenebis(salicylideneaminato)]cobaltate(I), [Co(salen)Na(thf)]n(thf = tetrahydrofuran), reacts with the cobalt(II) parent complex [Co(salen)] to form a neutral mixed-valence CoI–CoII complex in which two identical [Co(salen)] units act as equatorial ligands for a Na+ cation completing its octahedral co-ordination sphere with two thf molecules trans to each other.
F. Arena, C. Floriani and P. F. Zanazzi, J. Chem. Soc., Chem. Commun., 1987, 183 DOI: 10.1039/C39870000183
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