Issue 21, 1986

A simple, mild elimination of hydrogen halide from primary alkyl bromides and iodides

Abstract

Addition of a solution of a primary alkyl bromide or iodide and 1,8-diazabicyclo[5.4.0]undec-7-ene in tetrahydrofuran (THF) to a solution prepared from dichlorobis(triphenylphosphine)nickel, triphenylphosphine, and n-butyl-lithium in THF results in an elimination at room temperature to give, in most cases, the terminal alkene.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1986, 1621-1622

A simple, mild elimination of hydrogen halide from primary alkyl bromides and iodides

S. Jeropoulos and E. H. Smith, J. Chem. Soc., Chem. Commun., 1986, 1621 DOI: 10.1039/C39860001621

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