Chlorodifluoroamine reacts at 190 K in CH2Cl2 with [M(CO)Cl(PEt3)2](M = Ir or Rh) to give [M(CO)Cl2(PEt3)2(NF2)], characterised by 19F and 31 P n.m.r. spectroscopy (the 15N derivative was also obtained for M = Ir); the novel complexes decompose in solution at temperatures above 240 K, the products of decomposition including N2F4.
R. W. Cockman, E. A. V. Ebsworth and J. H. Holloway, J. Chem. Soc., Chem. Commun., 1986, 1622 DOI: 10.1039/C39860001622
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