Unusual activity of carbon monoxide on Co-tetraphenylporphyrin supported by TiO2 for the reduction of nitric oxide
Abstract
Carbon monoxide reduces nitric oxide at 50 °C at a much greater rate than hydrogen and very rapidly at 100 °C over Co-TPP-TiO2 indicating the effective activation of carbon monoxide as well as nitric oxide on the partially reduced Co ion of the supported complex.