SCHEDULED MAINTENANCE:
The observation of a 2H–13C coupling in the 2H n.m.r. spectrum of aphidicolin biosynthesized from [4-2H2,3-13C]mevalonic acid, has established the migration of a 9β-hydrogen atom to C-8 during the biosynthesis.
M. J. Ackland, J. R. Hanson, A. H. Ratcliffe and I. H. Sadler, J. Chem. Soc., Chem. Commun., 1982, 165 DOI: 10.1039/C39820000165
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