Iron(III) chloride-catalysed photo-oxidation of substituted olefins gave either gem-dichloro-ketones or α,ω-dichloro-ketones selectively, depending upon the substitution pattern of the substrates.
T. Sato, K. Maemoto and A. Kohda, J. Chem. Soc., Chem. Commun., 1981, 1116 DOI: 10.1039/C39810001116
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