Issue 21, 1981

Conversion of non-terminal alkenes into secondary alkyl t-butyl peroxides by peroxymercuriation and reduction with tributyltin hydride

Abstract

s-Butyl, 3-hexyl, cyclopentyl, and cyclohexyl t-butyl peroxides have been prepared in yields of 63, 24, 59, and 61%, respectively, by reducing with tributyltin hydride the peroxymercurials derived from the corresponding symmetrical alkenes.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1981, 1117-1118

Conversion of non-terminal alkenes into secondary alkyl t-butyl peroxides by peroxymercuriation and reduction with tributyltin hydride

A. J. Bloodworth and J. L. Courtneidge, J. Chem. Soc., Chem. Commun., 1981, 1117 DOI: 10.1039/C39810001117

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