Dialkylzinc compounds react with tertiary alkyl halides to afford the corresponding coupling products containing a quaternary carbon atom, thereby making geminal dialkylation of ketones or hydroalkylation of olefins possible.
M. T. Reetz, B. Wenderoth, R. Peter, R. Steinbach and J. Westermann, J. Chem. Soc., Chem. Commun., 1980, 1202 DOI: 10.1039/C39800001202
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