Ziegler–Natta catalysis: an alternative mechanism involving metallacycles
Abstract
Semi-empirical molecular orbital calculations suggest a new catalytic sequence for Ziegler–Natta polymerization involving a metallacyclopentane intermediate.
Semi-empirical molecular orbital calculations suggest a new catalytic sequence for Ziegler–Natta polymerization involving a metallacyclopentane intermediate.
R. J. McKinney, J. Chem. Soc., Chem. Commun., 1980, 490 DOI: 10.1039/C39800000490
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