X-Ray crystal structure and 113Cd n.m.r. spectrum of αβγδ-tetraphenyl-porphinatocadmium(II)-bis(dioxan) solvate
Abstract
The 113Cd Fourier transform n.m.r. spectrum of the title compound is characterized by a single resonance at ca. 422 p.p.m. deshielded from 0·1 M CdClO4 solution; its crystal structure shows an almost planar CdN4 system with only very weak axial interactions to dioxan molecules.