Tetranuclear La(III)-Ni(0) iodide and hydride complexes featuring a Ni(0)→La(III) dative bond were synthesized and characterized by NMR spectroscopy, X-ray diffraction and computational analysis. The hydrido complex showed insertion reactivity with carbodiimide, and isonitrile, while its reaction with p-tolunitrile led to a cyanide complex via C-N bond cleavage.
X. He, C. Wu, D. Hong, H. Fang and P. Cui, Chem. Commun., 2026, Accepted Manuscript , DOI: 10.1039/D5CC06726J
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