Issue 37, 2025, Issue in Progress
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RSC Advances

Tetrabutylammonium decatungstate-catalyzed hydroalkylation/alkoxylation of 3-methyleneisoindolin-1-ones with alcohols/ethers through hydrogen atom transfer process

Han Fu,a   Feixia Wang,a   Ziyan Wu,a   Xiaoyu Xie, ORCID logo *a   Yicheng Zhang,*a   Jie Liu ORCID logo *a  and  Lei Wang ORCID logo abc  

* Corresponding authors

a Key Laboratory of Green and Precise Synthetic Chemistry and Application, Ministry of Education, School of Chemistry and Chemical Engineering, Huaibei Normal University, Huaibei, Anhui 235000, P. R. China
E-mail: xiexiaoyu@chnu.edu.cn

b Advanced Research Institute and Department of Chemistry, Taizhou University, Taizhou, Zhejiang 318000, P. R. China

c College of Material Chemistry and Chemical Engineering, Key Laboratory of Organosilicon Chemistry and Material Technology, Ministry of Education, Hangzhou Normal University, Hangzhou, Zhejiang, P. R. China

Abstract

A highly efficient tetrabutylammonium decatungstate (TBADT)-catalyzed synthesis of isoindolinones using activated alkenes and alcohols/ethers via hydrogen atom transfer process was developed. A variety of functionalized isoindolinones were obtained in good yields with high selectivity and broad functional group tolerance.

Graphical abstract: Tetrabutylammonium decatungstate-catalyzed hydroalkylation/alkoxylation of 3-methyleneisoindolin-1-ones with alcohols/ethers through hydrogen atom transfer process

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Article information

DOI
https://doi.org/10.1039/D5RA05071E
Article type
Paper
Submitted
15 Jul 2025
Accepted
16 Aug 2025
First published
26 Aug 2025
This article is Open Access
Creative Commons BY-NC license

RSC Adv., 2025,15, 30285-30289

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Tetrabutylammonium decatungstate-catalyzed hydroalkylation/alkoxylation of 3-methyleneisoindolin-1-ones with alcohols/ethers through hydrogen atom transfer process

H. Fu, F. Wang, Z. Wu, X. Xie, Y. Zhang, J. Liu and L. Wang, RSC Adv., 2025, 15, 30285 DOI: 10.1039/D5RA05071E

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