Chiral intercalation in layered cyano-bridged metal frameworks

Bojie Gong; Qiangqiang Qiao; Yujing Liu; Huadong Yuan; Jianmin Luo; Yao Wang; Shihui Zou; Peng Shi; Xinyong Tao; Jianwei Nai

doi:10.1039/D5CC04225A

Chiral intercalation in layered cyano-bridged metal frameworks

Bojie Gong,^a Qiangqiang Qiao,^a Yujing Liu,

^a Huadong Yuan,^a Jianmin Luo,

^a Yao Wang,

^a Shihui Zou,

^a Peng Shi,^b Xinyong Tao

^a and Jianwei Nai

*^a

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* Corresponding authors

^a College of Materials Science and Engineering, Zhejiang University of Technology, Hangzhou 310014, China
E-mail: jwnai@zjut.edu.cn

^b Science and Education Integration College of Energy and Carbon Neutralization, Zhejiang University of Technology, Hangzhou 310014, China

Abstract

In this work, a series of chiral nanomaterials have been successfully constructed by intercalating chiral molecules of α-methylbenzylamine into diverse layered cyano-bridged metal frameworks through host–guest interaction. These unique layered chiral nanomaterials show enhanced CO₂ photoreduction activity with the CO production rate up to 40.4 mmol h⁻¹ g⁻¹.

Chemical Communications

Chiral intercalation in layered cyano-bridged metal frameworks

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Chiral intercalation in layered cyano-bridged metal frameworks

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