Aqueous–organic hybrid electrolyte stabilizing zinc metal anodes

Abstract

A novel, low-cost, and non-flammable electrolyte composed of dimethylformamide (DMF), H2O, and Zn(BF4)2 has been proposed. This electrolyte effectively suppresses side reactions by reducing the activity of H2O coordinated with Zn2+. Furthermore, it inhibits zinc dendrite growth through the formation of an in situ ZnF2 layer, which enables a remarkable cycling stability of up to 2550 cycles in Zn symmetric cells.

Graphical abstract: Aqueous–organic hybrid electrolyte stabilizing zinc metal anodes

Supplementary files

Article information

Article type
Communication
Submitted
15 Apr 2025
Accepted
10 Jun 2025
First published
16 Jun 2025

Chem. Commun., 2025, Advance Article

Aqueous–organic hybrid electrolyte stabilizing zinc metal anodes

L. Hu, Y. Song, X. Li, K. Hu and Y. Song, Chem. Commun., 2025, Advance Article , DOI: 10.1039/D5CC02088C

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