Ni–Co hexacyanoferrate hollow nanoprism with CN vacancy for electrocatalytic benzyl alcohol oxidation

Chenghang Lv; Liang Chen; Jingjing Bai; Hongyu Ruo; Yanlong Pan; Shoudong Xu; Jiaqi Chen; Ding Zhang; Chunli Guo

doi:10.1039/D4CC01606H

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Ni–Co hexacyanoferrate hollow nanoprism with CN vacancy for electrocatalytic benzyl alcohol oxidation†

Chenghang Lv,

^ab Liang Chen,

*^a Jingjing Bai,^a Hongyu Ruo,^a Yanlong Pan,^a Shoudong Xu,

^c Jiaqi Chen,^a Ding Zhang

^d and Chunli Guo

*^b

Author affiliations

* Corresponding authors

^a College of Chemistry, Taiyuan University of Technology, Taiyuan 030024, P. R. China
E-mail: chenliang@tyut.edu.cn

^b College of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan 030024, P. R. China
E-mail: guochunli@tyut.edu.cn

^c College of Chemical Engineering and Technology, Taiyuan University of Technology, Taiyuan 030024, P. R. China

^d School of Chemical Engineering and Pharmacy, Wuhan Institute of Technology, Wuhan 430205, P. R. China

Abstract

An innovative method to improve the oxidation efficiency of benzyl alcohol utilizes Ni–Co hexacyanoferrate hollow nanoprisms. Synthesized via a gentle self-sacrificial template method, this catalyst exhibits substantial catalytic activity and selectivity towards benzyl alcohol oxidation, facilitated by the strategic incorporation of Co to modulate CN vacancy density. Impressively, it achieves a current density of 10 mA cm⁻² at 1.33 V and a remarkable 98% efficiency in benzyl alcohol conversion at 1.4 V.

Download options Please wait...

Supplementary files

Supplementary information PDF (4066K)

Article information

DOI: https://doi.org/10.1039/D4CC01606H
Article type: Communication
Submitted: 08 Apr 2024
Accepted: 14 May 2024
First published: 15 May 2024

Download Citation

Chem. Commun., 2024,60, 5952-5955

Permissions

Request permissions

Ni–Co hexacyanoferrate hollow nanoprism with CN vacancy for electrocatalytic benzyl alcohol oxidation

C. Lv, L. Chen, J. Bai, H. Ruo, Y. Pan, S. Xu, J. Chen, D. Zhang and C. Guo, Chem. Commun., 2024, 60, 5952 DOI: 10.1039/D4CC01606H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications

Ni–Co hexacyanoferrate hollow nanoprism with CN vacancy for electrocatalytic benzyl alcohol oxidation†

Abstract

Supplementary files

Article information

Download Citation

Permissions

Ni–Co hexacyanoferrate hollow nanoprism with CN vacancy for electrocatalytic benzyl alcohol oxidation

Social activity

Search articles by author

Spotlight

Advertisements