Issue 46, 2024

Lewis base adducts of NpCl4

Abstract

Np(IV) Lewis base adducts were prepared by ligand substitution of NpCl4(DME)2. Using acetonitrile and pyridine, NpCl4(MeCN)4 (1) and NpCl4(pyr)4 (2) were isolated, respectively. Addition of t-butylbipyridine and triphenylphosphine oxide generated the respective Lewis base adducts, NpCl4(tBuBipy)2 (3) and NpCl4(OPPh3)2 (4). All species were fully characterized using spectroscopic and structural analyses.

Graphical abstract: Lewis base adducts of NpCl4

Supplementary files

Article information

Article type
Communication
Submitted
05 Apr 2024
Accepted
01 May 2024
First published
03 May 2024
This article is Open Access
Creative Commons BY license

Chem. Commun., 2024,60, 5956-5959

Lewis base adducts of NpCl4

L. M. Lopez, M. C. Uible, M. Zeller and S. C. Bart, Chem. Commun., 2024, 60, 5956 DOI: 10.1039/D4CC01560F

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