Issue 41, 2024

Intercalating a potassium–aqua complex cation into an α-MoO3 layer without reducing molybdenum: a potential storage system

Abstract

We have demonstrated a green aqueous synthesis of rod-shaped MoO3 material, [MoVI3O9{K(H2O)4}(CH3COO)]·H2O (2) intercalating potassium–aqua-complex acetate into its lamellar space, simply by ion-exchange of Co(II)–aqua-complex in compound [MoVI4O12(CH3COO)2{CoII(H2O)6}]·2H2O (1) by {K(H2O)4}+ in an aqueous solution of 1 and KCl. Compound 2 acts as a potential storage system of alkali metal ions.

Graphical abstract: Intercalating a potassium–aqua complex cation into an α-MoO3 layer without reducing molybdenum: a potential storage system

Supplementary files

Article information

Article type
Communication
Submitted
27 Mar 2024
Accepted
15 Apr 2024
First published
15 Apr 2024

Chem. Commun., 2024,60, 5439-5442

Intercalating a potassium–aqua complex cation into an α-MoO3 layer without reducing molybdenum: a potential storage system

D. Jana, S. S. Mishra and S. K. Das, Chem. Commun., 2024, 60, 5439 DOI: 10.1039/D4CC01400F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements