Issue 18, 2023

Dynamic hydrogen bubbling templated AgSn@SnOx electrocatalyst for selective electrochemical CO2 reduction: adjusting the binding energy of the HCOO* intermediate

Abstract

Core–shell AgSn@SnOx electrodes prepared via dynamic hydrogen bubbling templating and galvanic replacement demonstrated selective electrocatalytic reduction of CO2 towards HCOOH with a faradaic efficiency of 96 ± 4.9% and partial current density of −10.46 ± 0.35 mA cm−2. DFT calculations revealed that the catalyst expedites the production of formic acid via adjusting the binding energy of the HCOO* intermediate.

Graphical abstract: Dynamic hydrogen bubbling templated AgSn@SnOx electrocatalyst for selective electrochemical CO2 reduction: adjusting the binding energy of the HCOO* intermediate

Supplementary files

Article information

Article type
Communication
Submitted
06 Jul 2023
Accepted
04 Aug 2023
First published
07 Aug 2023

Catal. Sci. Technol., 2023,13, 5175-5179

Dynamic hydrogen bubbling templated AgSn@SnOx electrocatalyst for selective electrochemical CO2 reduction: adjusting the binding energy of the HCOO* intermediate

H. G. El-Aqapa, I. M. Badawy, G. E. Khedr, A. M. Agour, D. M. Sayed, M. M. Taha and N. K. Allam, Catal. Sci. Technol., 2023, 13, 5175 DOI: 10.1039/D3CY00939D

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