Issue 32, 2023
From the journal:

Chemical Communications

Spectroscopic and reactive characterization of mixed-metal Fe–Cr trimer nodes in metal–organic framework MIL-100†

Jacklyn N. Hall ORCID logo a  and  Praveen Bollini ORCID logo *a  

* Corresponding authors

a William A. Brookshire Department of Chemical and Biomolecular Engineering, University of Houston, Houston, TX 77204, USA
E-mail: ppbollini@uh.edu

Abstract

Metal–organic framework MIL-100 is synthesized featuring heterometallic Fe and Cr M3O nodes where mixing of the metals within the nodes is evidenced using a combination of in situ IR spectroscopy, NO titrations, and CO oxidation kinetics. Reactivity data indicate distinctive properties of the bimetallic nodes.

Graphical abstract: Spectroscopic and reactive characterization of mixed-metal Fe–Cr trimer nodes in metal–organic framework MIL-100

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Article information

DOI
https://doi.org/10.1039/D3CC00100H
Article type
Communication
Submitted
07 Jan 2023
Accepted
22 Mar 2023
First published
22 Mar 2023

Chem. Commun., 2023,59, 4758-4761

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Spectroscopic and reactive characterization of mixed-metal Fe–Cr trimer nodes in metal–organic framework MIL-100

J. N. Hall and P. Bollini, Chem. Commun., 2023, 59, 4758 DOI: 10.1039/D3CC00100H

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