Issue 50, 2022, Issue in Progress

Balanced change in crystal unit cell volume and strain leads to stable halide perovskite with high guanidinium content

Abstract

Up-to-date studies propose that strain in halide perovskites is one of the key factors that determine a device's efficiency and stability. Here, we show a systematic approach to characterize the phenomenon in the standard methylammonium lead iodine (MAPbI3) perovskite system by: (i) the substitution of some MA by guanidinium (Gu); (ii) the incorporation of PbS quantum dot (QD) additives and (iii) addition of both Gu and PbS at the same time. We studied the effect of these incorporations on the film strain and crystal cell unit volume, and on the solar cell device efficiency and stability. Gu cations and PbS QDs affect the strain, the former due to the relatively large dimensions of Gu, and the latter due to the lattice matching parameters. With the control of Gu and PbS QD content, higher performance and longer solar cell stability are obtained. We demonstrated that the presence of Gu and PbS QDs alters the structure of perovskite, in terms of modification of the unit cell volume and strain. The greater size of Gu cations produces a MAPbI3 unit cell volume expansion as Gu is incorporated, modifying the strain from compressive to tensile. PbS QDs aid Gu incorporation, producing a unit cell volume expansion. In the case of 15% mol Gu incorporation, the addition of PbS QDs modifies strain from compressive to tensile, limiting the deleterious effect. At the same time the unit cell volume is less affected, increasing the solar cell stability. Our work shows that the control of compressive strain and the unit cell volume expansion lead to a 50% increase in T80, the time in which the PCE decreases to 80% of its original value, increasing the T80 value from 120 to 187 days under air conditions. Moreover it highlights the importance of exploiting not only the control of the strain induced by internal component, the cation, but also the strain induced by the external component, the QD, associated instead with critical volume variation of metastable perovskite unit cell volume.

Graphical abstract: Balanced change in crystal unit cell volume and strain leads to stable halide perovskite with high guanidinium content

Supplementary files

Article information

Article type
Paper
Submitted
13 Oct 2022
Accepted
04 Nov 2022
First published
14 Nov 2022
This article is Open Access
Creative Commons BY-NC license

RSC Adv., 2022,12, 32630-32639

Balanced change in crystal unit cell volume and strain leads to stable halide perovskite with high guanidinium content

P. Serafini, A. F. Gualdrón-Reyes, R. S. Sánchez, E. M. Barea, S. Masi and I. Mora-Seró, RSC Adv., 2022, 12, 32630 DOI: 10.1039/D2RA06473A

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