Hydrogenation of cage-opened C60 derivatives mediated by frustrated Lewis pairs

Yoshifumi Hashikawa; Yasujiro Murata

doi:10.1039/D1OB02316K

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Hydrogenation of cage-opened C₆₀ derivatives mediated by frustrated Lewis pairs†

Yoshifumi Hashikawa

^a and Yasujiro Murata

*^a

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^a Institute for Chemical Research, Kyoto University, Uji, Kyoto 611-0011, Japan

Abstract

Multiply-carbonylated fullerene derivatives were found to work as one component in frustrated Lewis pairs which caused an Si–H bond activation in the presence of B(C₆F₅)₃, leading to the carbonyl hydrogenation in up to 99% yield. The Lewis acid-mediated reductive arylation also took place to furnish a corresponding ketal derivative.

This article is part of the themed collection: Supramolecular chemistry in OBC

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Article information

DOI: https://doi.org/10.1039/D1OB02316K
Article type: Communication
Submitted: 04 Dec 2021
Accepted: 10 Jan 2022
First published: 14 Jan 2022

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Org. Biomol. Chem., 2022,20, 1000-1003

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Hydrogenation of cage-opened C₆₀ derivatives mediated by frustrated Lewis pairs

Y. Hashikawa and Y. Murata, Org. Biomol. Chem., 2022, 20, 1000 DOI: 10.1039/D1OB02316K

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Organic & Biomolecular Chemistry