Issue 88, 2022

Stabilizing large pores in a flexible metal–organic framework via chemical cross-linking

Abstract

A barrier to the isoreticular expansion of flexible metal–organic frameworks is their complex breathing behavior, which can lead to pore closure upon solvent exchange and removal. Here we show that chemical cross-linking stabilizes the open form of a flexible aluminum framework with large 17 Å pores.

Graphical abstract: Stabilizing large pores in a flexible metal–organic framework via chemical cross-linking

Supplementary files

Article information

Article type
Communication
Submitted
31 Aug 2022
Accepted
13 Oct 2022
First published
20 Oct 2022

Chem. Commun., 2022,58, 12361-12364

Stabilizing large pores in a flexible metal–organic framework via chemical cross-linking

D. S. Rollins, J. Geary, A. H. Wong and D. J. Xiao, Chem. Commun., 2022, 58, 12361 DOI: 10.1039/D2CC04829A

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