Issue 88, 2022

One-pot heteroannulation toward phosphaperylene diimides with high luminescence and out-of-plane anisotropy

Abstract

P-heteroannulation on perylene diimides in one pot is presented. The resulting phosphaperylene diimides demonstrate unique molecular structures with an out-of-plane dipole moment of 8.10 D. Photophysical characterization reveals degenerated LUMO levels as low as −4.4 eV and remarkable absorption redshifts extending to 579 nm. High fluorescence quantum yields (ϕF) of up to 94% make them promising photoluminescent materials.

Graphical abstract: One-pot heteroannulation toward phosphaperylene diimides with high luminescence and out-of-plane anisotropy

Supplementary files

Article information

Article type
Communication
Submitted
30 Aug 2022
Accepted
07 Oct 2022
First published
07 Oct 2022

Chem. Commun., 2022,58, 12321-12324

One-pot heteroannulation toward phosphaperylene diimides with high luminescence and out-of-plane anisotropy

Z. Ma, Y. Liu, Z. Wang and W. Jiang, Chem. Commun., 2022, 58, 12321 DOI: 10.1039/D2CC04784E

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