Issue 71, 2022
From the journal:

Chemical Communications

Photoactive carbon monoxide-releasing coordination polymer particles†

Arnau Carné-Sánchez, ORCID logo *ab   Shuya Ikemura,ac   Reiko Sakaguchi,a   Gavin A. Craig ORCID logo *ad  and  Shuhei Furukawa ORCID logo *ac  

* Corresponding authors

a Institute for Integrated Cell-Material Sciences (WPI-iCeMS), Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501, Japan
E-mail: shuhei.furukawa@icems.kyoto-u.ac.jp

b Catalan Institute of Nanoscience and Nanotechnology (ICN2) CSIC and The Barcelona Institute of Science and Technology Campus UAB, Bellaterra, 08193 Barcelona, Spain

c Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan

d Department of Pure and Applied Chemistry, University of Strathclyde, G1 1XL Glasgow, Scotland, UK

Abstract

We report the synthesis of photoactive carbon monoxide-releasing coordination polymer particles through the assembly of Mn(I) carbonyl complexes with bis(imidazole) ligands. The use of Mn(I) carbonyl complexes as metallic nodes in the coordination network avoids the potential for aggregation-induced self-quenching, favouring their use in the solid state.

Graphical abstract: Photoactive carbon monoxide-releasing coordination polymer particles

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Article information

DOI
https://doi.org/10.1039/D2CC03907A
Article type
Communication
Submitted
13 Jul 2022
Accepted
11 Aug 2022
First published
11 Aug 2022

Chem. Commun., 2022,58, 9894-9897

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Photoactive carbon monoxide-releasing coordination polymer particles

A. Carné-Sánchez, S. Ikemura, R. Sakaguchi, G. A. Craig and S. Furukawa, Chem. Commun., 2022, 58, 9894 DOI: 10.1039/D2CC03907A

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