Cobalt-plasma treatment enables structural reconstruction of a CoOx/BiVO4 composite for efficient photoelectrochemical water splitting

Abstract

Cobalt-plasma sparked by a pulsed laser was utilized for the first time to modify a BiVO₄ photoanode, inducing surface structural reconstruction and CoO_x/BiVO₄ composite construction. Combining charge redistribution and cobalt, the center of hole accumulation and catalytic activity, the photoanode with optimized charge transfer capacity exhibits a 3 times improvement in photoelectrochemical water oxidation performance.