Cd2(IO3)(PO4) and Cd1.62Mg0.38(IO3)(PO4): metal iodate-phosphates with large SHG responses and wide band gaps

Abstract

The first NLO-active metal iodate-phosphates, namely, Cd₂(IO₃)(PO₄) and Cd_1.62Mg_0.38(IO₃)(PO₄) (1 and 2), with three types of NLO groups, have been reported. 1 and 2 are isostructural and the structure of 1 features a 3D network formed by the Cd₄(IO₃)_8/4(PO₄)_6/3 groups. 1 and 2 with strong SHG signals of 4 × and 3.5 × KH₂PO₄ are promising SHG materials in the visible region.