Well-organised two-dimensional self-assembly controlled by in situ formation of a Cu(II)-coordinated rufigallol derivative: a scanning tunnelling microscopy study

Yoshihiro Kikkawa; Mayumi Nagasaki; Seiji Tsuzuki; Thierry N. J. Fouquet; Sayaka Nakamura; Yasumasa Takenaka; Yasuo Norikane; Kazuhisa Hiratani

doi:10.1039/D1CC05991B

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Well-organised two-dimensional self-assembly controlled by in situ formation of a Cu(ii)-coordinated rufigallol derivative: a scanning tunnelling microscopy study†

Yoshihiro Kikkawa,

*^a Mayumi Nagasaki,^a Seiji Tsuzuki,

^a Thierry N. J. Fouquet,

^a Sayaka Nakamura,^a Yasumasa Takenaka,

^b Yasuo Norikane

^a and Kazuhisa Hiratani^a

Author affiliations

* Corresponding authors

^a National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba Central 5, 1-1-1 Higashi, Tsukuba, Ibaraki 305-8565, Japan
E-mail: y.kikkawa@aist.go.jp

^b Bioplastic Research Team, RIKEN Center for Sustainable Resource Science, 2-1 Hirosawa, Wako, Saitama 351-0198, Japan

Abstract

The two-dimensional self-assembly of rufigallol derivatives and their metal coordination were studied by scanning tunnelling microscopy. Ex situ Cu(II)-coordinated rufigallol derivatives exhibited columnar structures with some defects, whereas regular and linear structures were formed upon in situ metal coordination at solid/liquid interfaces.

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Article information

DOI: https://doi.org/10.1039/D1CC05991B
Article type: Communication
Submitted: 25 Oct 2021
Accepted: 02 Jan 2022
First published: 06 Jan 2022

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Chem. Commun., 2022,58, 1752-1755

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Well-organised two-dimensional self-assembly controlled by in situ formation of a Cu(II)-coordinated rufigallol derivative: a scanning tunnelling microscopy study

Y. Kikkawa, M. Nagasaki, S. Tsuzuki, T. N. J. Fouquet, S. Nakamura, Y. Takenaka, Y. Norikane and K. Hiratani, Chem. Commun., 2022, 58, 1752 DOI: 10.1039/D1CC05991B

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Chemical Communications

Well-organised two-dimensional self-assembly controlled by in situ formation of a Cu(ii)-coordinated rufigallol derivative: a scanning tunnelling microscopy study†

Abstract

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Well-organised two-dimensional self-assembly controlled by in situ formation of a Cu(II)-coordinated rufigallol derivative: a scanning tunnelling microscopy study

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