Issue 60, 2022

Rapid access to organic triflates based on flash generation of unstable sulfonium triflates in flow

Abstract

Flash (extremely fast) electrochemical generation of unstable arylbis(arylthio)sulfonium triflates [ArS(ArSSAr)]+ [OTf] that are unsuitable for accumulation in batch processes was achieved within 10 s in a divided-type flow electrochemcial reactor, enabling one-flow access to vinyl triflates, short-lived oxocarbenium triflates and glycosyl triflates.

Graphical abstract: Rapid access to organic triflates based on flash generation of unstable sulfonium triflates in flow

Supplementary files

Article information

Article type
Communication
Submitted
26 Apr 2022
Accepted
30 Jun 2022
First published
01 Jul 2022

Chem. Commun., 2022,58, 8344-8347

Rapid access to organic triflates based on flash generation of unstable sulfonium triflates in flow

M. Takumi, H. Sakaue, D. Shibasaki and A. Nagaki, Chem. Commun., 2022, 58, 8344 DOI: 10.1039/D2CC02344J

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