Issue 46, 2022
From the journal:

Chemical Communications

Iodine-doped covalent organic frameworks with coaxially stacked cruciform anthracenes for high Hall mobility†

Yunyang Zhu,a   Weijun Weng,a   Ting Zhou,a   Zheng Lin,a   Ning Ding,a   Phornphimon Maitarad, ORCID logo b   Changchun Wang ORCID logo a  and  Jia Guo ORCID logo *a  

* Corresponding authors

a State Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science, Fudan University, Shanghai 200438, P. R. China
E-mail: guojia@fudan.edu.cn

b Research Center of Nano Science and Technology, Department of Chemistry, College of Science, Shanghai University, Shanghai 200444, P. R. China

Abstract

Cruciform anthracene building blocks are designed to construct an electroactive two-dimensional covalent organic framework (COF). Upon doping with iodine, cationic radicals are produced on the COF to exhibit structure-enhanced charge transfer properties with a low activation energy (0.13 eV) and a high Hall mobility (10.5 cm2 V−1 s−1).

Graphical abstract: Iodine-doped covalent organic frameworks with coaxially stacked cruciform anthracenes for high Hall mobility

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Article information

DOI
https://doi.org/10.1039/D2CC01721K
Article type
Communication
Submitted
28 Mar 2022
Accepted
04 May 2022
First published
06 May 2022

Chem. Commun., 2022,58, 6606-6609

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Iodine-doped covalent organic frameworks with coaxially stacked cruciform anthracenes for high Hall mobility

Y. Zhu, W. Weng, T. Zhou, Z. Lin, N. Ding, P. Maitarad, C. Wang and J. Guo, Chem. Commun., 2022, 58, 6606 DOI: 10.1039/D2CC01721K

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