Issue 43, 2021
From the journal:

Chemical Science

Visible light-induced oxidative N-dealkylation of alkylamines by a luminescent osmium(vi) nitrido complex†

Jing Xiang, ORCID logo *a   Min Peng,a   Yi Pan, ORCID logo b   Li-Juan Luo,a   Shun-Cheung Cheng,b   Xin-Xin Jin,a   Shek-Man Yiu,b   Wai-Lun Man, ORCID logo c   Chi-Chiu Ko, ORCID logo b   Kai-Chung Lau ORCID logo *b  and  Tai-Chu Lau ORCID logo *b  

* Corresponding authors

a College of Chemistry and Environmental Engineering, Yangtze University, Jingzhou 434020, Hubei, P. R. China
E-mail: xiangjing@yangtzeu.edu.cn

b Department of Chemistry, City University of Hong Kong, Tat Chee Avenue, Kowloon Tong, Hong Kong, China
E-mail: bhtclau@cityu.edu.hk, kaichung@cityu.edu.hk

c Department of Chemistry, Hong Kong Baptist University, Kowloon Tong, Hong Kong 999077, People's Republic of China

Abstract

N-Dealkylation of amines by metal oxo intermediates (M[double bond, length as m-dash]O) is related to drug detoxification and DNA repair in biological systems. In this study, we report the first example of N-dealkylation of various alkylamines by a luminescent osmium(VI) nitrido complex induced by visible light.

Graphical abstract: Visible light-induced oxidative N-dealkylation of alkylamines by a luminescent osmium(vi) nitrido complex

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Article information

DOI
https://doi.org/10.1039/D1SC04369B
Article type
Edge Article
Submitted
10 Aug 2021
Accepted
08 Oct 2021
First published
09 Oct 2021
This article is Open Access

All publication charges for this article have been paid for by the Royal Society of Chemistry
Creative Commons BY-NC license

Chem. Sci., 2021,12, 14494-14498

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Visible light-induced oxidative N-dealkylation of alkylamines by a luminescent osmium(VI) nitrido complex

J. Xiang, M. Peng, Y. Pan, L. Luo, S. Cheng, X. Jin, S. Yiu, W. Man, C. Ko, K. Lau and T. Lau, Chem. Sci., 2021, 12, 14494 DOI: 10.1039/D1SC04369B

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