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Visible light induces C–C-bond cleavage reactions of ketones, which can be utilized for N-acylations of sulfoximines. No (photo)catalyst is required, and the reactions occur at ambient temperature in air. The substrate scope is broad for both ketones and sulfoximines. For converting NH-sulfoximines, the presence of NBS is essential.

Graphical abstract: Visible light-induced C–C bond cleavage in a multicomponent reaction cascade allowing acylations of sulfoximines with ketones

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