Issue 41, 2021
From the journal:

Dalton Transactions

Straightforward formation of dianionic acetonylate: self-assembly of mercury(ii) with pyridyl donor ligands in acetone†

Kangsan Hong,a   Sangwoo Lim,a   Heehun Moon,a   Dongwon Kim, ORCID logo a   Dongwook Kim ORCID logo b  and  Ok-Sang Jung ORCID logo *a  

* Corresponding authors

a Department of Chemistry, Pusan National University, Busan 46241, Republic of Korea
E-mail: oksjung@pusan.ac.kr
Fax: (+82) 51-5163522
Tel: (+82) 51-5103240

b Center for Hydrocarbon Functionalizations, IBS, Daejon 34141, Republic of Korea

Abstract

Self-assembly of Hg(ClO4)2 with a new bidentate ligand (L) in acetone at room temperature produces single crystals consisting of unusual discrete tetranuclear complexes [Hg4(ClO4)4(CH2COCH2)2L2]·CH3COCH3via straightforward formation of dianionic acetonylate −CH2COCH2− in a quantitative yield.

Graphical abstract: Straightforward formation of dianionic acetonylate: self-assembly of mercury(ii) with pyridyl donor ligands in acetone

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Article information

DOI
https://doi.org/10.1039/D1DT03115E
Article type
Communication
Submitted
14 Sep 2021
Accepted
06 Oct 2021
First published
06 Oct 2021

Dalton Trans., 2021,50, 14547-14550

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Straightforward formation of dianionic acetonylate: self-assembly of mercury(II) with pyridyl donor ligands in acetone

K. Hong, S. Lim, H. Moon, D. Kim, D. Kim and O. Jung, Dalton Trans., 2021, 50, 14547 DOI: 10.1039/D1DT03115E

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