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Abstract | Cited by

The first protocol for the synthesis of unsymmetrical bifunctional 1,1,3,3-tetramethyldisiloxane derivatives via subsequent hydrosilylation of alkenes and alkynes is presented. The methodology described has vast functional group tolerance and is extremely efficient towards the formation of novel disiloxane-based building blocks.

Graphical abstract: Synthesis of bifunctional disiloxanes via subsequent hydrosilylation of alkenes and alkynes

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