Synthesis of bifunctional disiloxanes via subsequent hydrosilylation of alkenes and alkynes

Jakub Szyling; Rafał Januszewski; Kamila Jankowska; Jędrzej Walkowiak; Ireneusz Kownacki; Adrian Franczyk

doi:10.1039/D1CC01253C

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Synthesis of bifunctional disiloxanes via subsequent hydrosilylation of alkenes and alkynes†‡

Jakub Szyling,

^ab Rafał Januszewski,

^ab Kamila Jankowska,

^ab Jędrzej Walkowiak,

^a Ireneusz Kownacki

^ab and Adrian Franczyk

*^a

Author affiliations

* Corresponding authors

^a Center for Advanced Technology, Adam Mickiewicz University in Poznań, Uniwersytetu Poznańskiego 10, Poznań 61-614, Poland
E-mail: adrian.franczyk@amu.edu.pl

^b Faculty of Chemistry, Adam Mickiewicz University in Poznań, Uniwersytetu Poznańskiego 8, Poznań 61-614, Poland

Abstract

The first protocol for the synthesis of unsymmetrical bifunctional 1,1,3,3-tetramethyldisiloxane derivatives via subsequent hydrosilylation of alkenes and alkynes is presented. The methodology described has vast functional group tolerance and is extremely efficient towards the formation of novel disiloxane-based building blocks.

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Article information

DOI: https://doi.org/10.1039/D1CC01253C
Article type: Communication
Submitted: 08 Mar 2021
Accepted: 26 Mar 2021
First published: 08 Apr 2021
This article is Open Access

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Chem. Commun., 2021,57, 4504-4507

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Synthesis of bifunctional disiloxanes via subsequent hydrosilylation of alkenes and alkynes

J. Szyling, R. Januszewski, K. Jankowska, J. Walkowiak, I. Kownacki and A. Franczyk, Chem. Commun., 2021, 57, 4504 DOI: 10.1039/D1CC01253C

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Chemical Communications

Synthesis of bifunctional disiloxanes via subsequent hydrosilylation of alkenes and alkynes†‡

Abstract

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Synthesis of bifunctional disiloxanes via subsequent hydrosilylation of alkenes and alkynes

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