Issue 37, 2021

Chain-capper effect to bias the amplification of asymmetry in supramolecular polymers

Abstract

The kinetically controlled amplification of asymmetry experienced in the co-assembly of chiral tribiphenylaminetricarboxamides (S)-1 and (R)-1 is investigated. The formation of metastable monomeric species through intramolecular H-bonds retards the efficient amplification of asymmetry due to a chain-capper effect.

Graphical abstract: Chain-capper effect to bias the amplification of asymmetry in supramolecular polymers

Supplementary files

Article information

Article type
Communication
Submitted
08 Feb 2021
Accepted
30 Mar 2021
First published
30 Mar 2021

Chem. Commun., 2021,57, 4500-4503

Chain-capper effect to bias the amplification of asymmetry in supramolecular polymers

C. Naranjo, Y. Dorca, G. Ghosh, R. Gómez, G. Fernández and L. Sánchez, Chem. Commun., 2021, 57, 4500 DOI: 10.1039/D1CC00740H

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