Issue 5, 2021
From the journal:

Chemical Communications

Azide–alkyne cycloadditions in a vortex fluidic device: enhanced “on water” effects and catalysis in flow†

Gabriela Oksdath-Mansilla, ORCID logo ab   Renata L. Kucera,b   Justin M. Chalker ORCID logo *b  and  Colin L. Raston ORCID logo *b  

* Corresponding authors

a INFIQC-CONICET-UNC, Dpto. de Química Orgánica, Facultad de Ciencias Químicas, Universidad Nacional de Córdoba, Córdoba, Argentina

b Institute for Nanoscale Science and Technology, College of Science and Engineering, Flinders University, Bedford Park, South Australia, Australia
E-mail: justin.chalker@flinders.edu.au, colin.raston@flinders.edu.au

Abstract

The Vortex Fluidic Device is a flow reactor that processes reactions in thin films. Running the metal-free azide–alkyne cycloaddition in this reactor revealed a dramatic enhancement of the “on water” effect. For the copper-catalyzed azide–alkyne cycloaddition, stainless steel or copper jet feeds were effective reservoirs of active copper catalyst.

Graphical abstract: Azide–alkyne cycloadditions in a vortex fluidic device: enhanced “on water” effects and catalysis in flow

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Article information

DOI
https://doi.org/10.1039/D0CC04401F
Article type
Communication
Submitted
25 Jun 2020
Accepted
10 Dec 2020
First published
14 Dec 2020

Chem. Commun., 2021,57, 659-662

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Azide–alkyne cycloadditions in a vortex fluidic device: enhanced “on water” effects and catalysis in flow

G. Oksdath-Mansilla, R. L. Kucera, J. M. Chalker and C. L. Raston, Chem. Commun., 2021, 57, 659 DOI: 10.1039/D0CC04401F

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