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Accessing alkyl boronic esters via visible light-mediated decarboxylative addition reactions of redox-active esters

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Abstract

A general and facile approach for the synthesis of alkyl boronic esters via visible light-mediated decarboxylative radical addition of redox-active esters to vinyl boronic ester is presented. The reaction features mild, metal-free reaction conditions and broad substrate scope covering primary, secondary, and tertiary acids, as well as amino acids and drugs.

Graphical abstract: Accessing alkyl boronic esters via visible light-mediated decarboxylative addition reactions of redox-active esters

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Article information


Submitted
13 Apr 2020
Accepted
13 Jun 2020
First published
17 Jun 2020

Org. Chem. Front., 2020, Advance Article
Article type
Research Article

Accessing alkyl boronic esters via visible light-mediated decarboxylative addition reactions of redox-active esters

X. Shu, R. Xu, Q. Ma and S. Liao, Org. Chem. Front., 2020, Advance Article , DOI: 10.1039/D0QO00440E

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