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Issue 15, 2020
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Accessing alkyl boronic esters via visible light-mediated decarboxylative addition reactions of redox-active esters

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Abstract

A general and facile approach for the synthesis of alkyl boronic esters via visible light-mediated decarboxylative radical addition of redox-active esters to vinyl boronic ester is presented. The reaction features mild, metal-free reaction conditions and broad substrate scope covering primary, secondary, and tertiary acids, as well as amino acids and drugs.

Graphical abstract: Accessing alkyl boronic esters via visible light-mediated decarboxylative addition reactions of redox-active esters

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Article information


Submitted
13 Apr 2020
Accepted
13 Jun 2020
First published
17 Jun 2020

Org. Chem. Front., 2020,7, 2003-2007
Article type
Research Article

Accessing alkyl boronic esters via visible light-mediated decarboxylative addition reactions of redox-active esters

X. Shu, R. Xu, Q. Ma and S. Liao, Org. Chem. Front., 2020, 7, 2003 DOI: 10.1039/D0QO00440E

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