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Roquefornine A, a sesterterpenoid with a 5/6/5/5/6-fused ring system from the fungus Penicillium roqueforti YJ-14

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Abstract

Roquefornine A, a sesterterpenoid with an unprecedented 5/6/5/5/6-membered pentacyclic system, was characterized from Penicillium roqueforti YJ-14. Its structure was determined by extensive spectroscopic analyses, [Rh2(OCOCF3)4]-induced CD data, and DP4+ calculations. A biosynthetic pathway, cytotoxicity, and anti-inflammatory activity were also discussed.

Graphical abstract: Roquefornine A, a sesterterpenoid with a 5/6/5/5/6-fused ring system from the fungus Penicillium roqueforti YJ-14

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Article information


Submitted
07 Mar 2020
Accepted
24 Apr 2020
First published
28 Apr 2020

Org. Chem. Front., 2020, Advance Article
Article type
Research Article

Roquefornine A, a sesterterpenoid with a 5/6/5/5/6-fused ring system from the fungus Penicillium roqueforti YJ-14

J. Wang, Y. Shu, J. Hu, R. Liu, X. Cai, C. Sun, D. Gan, D. Zhou, R. Mei, H. Ding, X. Zhang, L. Cai and Z. Ding, Org. Chem. Front., 2020, Advance Article , DOI: 10.1039/D0QO00301H

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